Hypercrosslinked Hydrogel Composite Membranes Targeted for Removal of Volatile Organic Compounds via Selective Solution-Diffusion in Membrane Distillation.

Membrane distillation (MD) has attracted considerable interest in hypersaline wastewater treatment. However, its practicability is severely impeded by the ineffective interception of volatile organic compounds (VOCs), which seriously affects the product water quality. Herein, a hypercrosslinked alginate (Alg)/aluminum (Al) hydrogel composite membrane is facilely fabricated via Alg pregel formation and ionic crosslinking for efficient VOC interception. The obtained MD membrane shows a sufficient phenol rejection of 99.52% at the phenol concentration of 100 ppm, which is the highest rejection among the reported MD membranes. Moreover, the hydrogel composite membrane maintains a high phenol interception (>99%), regardless of the feed temperature, initial phenol concentration, and operating time. Diffusion experiments and molecular dynamics simulation verify that the selective diffusion is the dominant mechanism for VOCs-water separation. Phenol experiences a higher energy barrier to pass through the dense hydrogel layer compared to water molecules as the stronger interaction between phenol-Alg compared with water-Alg. Benefited from the dense and hydratable Alg/Al hydrogel layer, the composite membrane also exhibits robust resistance to wetting and fouling during long-term operation. The superior VOCs removal efficiency and excellent durability endow the hydrogel composite membrane with a promising application for treating complex wastewater containing both volatile and nonvolatile contaminants.

NCI Cancer Research Data Commons: Resources to Share Key Cancer Data.

Since 2014, the National Cancer Institute (NCI) has launched a series of data commons as part of the Cancer Research Data Commons (CRDC) ecosystem housing genomic, proteomic, imaging, and clinical data to support cancer research and promote data sharing of NCI-funded studies. This review describes each data commons (Genomic Data Commons, Proteomic Data Commons, Integrated Canine Data Commons, Cancer Data Service, Imaging Data Commons, and Clinical and Translational Data Commons), including their unique and shared features, accomplishments, and challenges. Also discussed is how the CRDC data commons implement Findable, Accessible, Interoperable, Reusable (FAIR) principles and promote data sharing in support of the new NIH Data Management and Sharing Policy.

Molecular insights into the adsorption and penetration of oil droplets on hydrophobic membrane in membrane distillation.

Membrane fouling induced by oily substances significantly constrains membrane distillation performance in treating hypersaline oily wastewater. Overcoming this challenge necessitates a heightened fundamental understanding of the oil fouling phenomenon. Herein, the adsorption and penetration mechanism of oil droplets on hydrophobic membranes in membrane distillation process was investigated at the molecular level. Our results demonstrated that the adsorption and penetration of oil droplets were divided into four stages, including the free stage, contact stage, spreading stage, and equilibrium stage. Due to the extensive non-polar surface distribution of the polytetrafluoroethylene (PTFE) membrane (comprising 95.41 %), the interaction between oil molecules and PTFE was primarily governed by van der Waals interaction. Continuous oil droplet membrane fouling model revealed that the new oil droplet molecules preferred to penetrate into membrane pores where oil droplets already existed. The penetration of resin (a component of medium-quality oil droplets) onto PTFE membrane pores required the "pre-paving" of light crude oil. Finally, the ΔE quantitative structure-activity relationships (QSAR) models were developed to evaluate the penetration mechanism of pollutant molecules on the PTFE membrane. This research provides new insights for improving sustainable membrane distillation technologies in treating saline oily wastewater.

Insights into the pH-dependent interactions of sulfadiazine antibiotic with soil particle models.

Sulfonamide antibiotics (SAs) are widely used as a broad-spectrum antibiotic, leading to global concerns due to their potential soil accumulation and subsequent effects on ecosystems. SAs often exhibit remarkable environmental persistence, necessitating further investigation to uncover the ultimate destiny of these molecules. In this work, molecular dynamics simulations combined with complementary quantum chemistry calculations were employed to investigate the influence of pH on the behavior of sulfadiazine (SDZ, a typical SAs) in soil particle models (silica, one of the main components of soil). Meanwhile, the quantification of SDZ molecules aggregation potential onto silica was further extended. SDZ molecules tend to form a monolayer on the soil surface under acidic conditions while forming aggregated adsorption on the surface under neutral conditions. Due to the hydrophilicity of the silica, multiple hydration layers would form on its surface, hindering the further adsorption of SDZ molecules on its surface. The calculated soil-water partition coefficient (Psoil/water) of SDZ+ and SDZ were 9.01 and 7.02, respectively. The adsorption evaluation and mechanisms are useful in controlling the migration and transformation of SAs in the soil environment. These findings provide valuable insights into the interactions between SDZ and soil components, shedding light on its fate and transport in the environment.

Synergistic Effect of Ti3C2Tx MXene Nanosheets and Tannic Acid-Fe3+ Network in Constructing High-Performance Hydrogel Composite Membrane for Photothermal Membrane Distillation.

Photothermal membrane distillation (PMD) has emerged as a promising and sustainable approach for seawater desalination and wastewater purification. However, the wide application of the technique is severely impeded by low freshwater production and membrane fouling/wetting issues. Herein, we developed an advanced hydrogel-engineered membrane with simultaneously enhanced photothermal conversion capacity and desired fouling and wetting resistance for PMD. By the synergies of photothermal Ti3C2Tx MXene nanosheets and the tannic acid-Fe3+ network in the hydrogel, the membrane was endowed with excellent surface self-heating ability, yielding the highest freshwater production rate (1.71 kg m-2 h-1) and photothermal efficiency among the fabricated hydrogel composite membranes under 1 sun irradiation. Meanwhile, the PMD membrane could robustly resist oil-induced fouling and surfactant-induced wetting, significantly extending the membrane lifespan in treating contaminated saline water. Furthermore, when desalinating real seawater, the membrane exhibited superior durability with a stable vapor flux and excellent ion rejection (e.g., 99.24% for boron) for 100 h.

Joule Heating-Assisted Crude Oil Purification by a Poly(pyrrole)-Modified Microfibril Cellulose Membrane.

Using membrane materials to purify viscous watery oil from industrial production processes and accidental oil spills is of great importance but still challenging. Based on the excellent electrical conductivity and electric-thermal conversion of poly(pyrrole) (PPy), a hydrophobic PPy-modified micro-fibrillated cellulose membrane (P-CP) was successfully prepared. The size of the P-CP membrane can be customized to meet specific requirements. In this research, the membrane diameter is capable of reaching 24 cm. By applying a voltage ranging from 0 to 12 V, the surface temperature of the P-CP membrane can be elevated to roughly 120 °C. After 10 cycles of heating and cooling under 12 V voltage, the electric-thermal curves, surface hydrophobicity, and pore structure of P-CP membrane can remain stable, which suggests remarkable electric-thermal stability and reliability despite prolonged operation. The P-CP membrane shows good linearity between voltage and current (R2 = 0.997) and easy temperature control from room temperature to ∼120 °C at low supply voltage (0-12 V). Under the condition of 12 V power supply and self-gravity, the separation flux of the P-CP membrane for water-in-oil (W/O) emulsions (kerosene, diesel) is 2-3 times higher than that at room temperature, and the separation efficiency is also improved. Importantly, the P-CP membrane shows excellent separation performance for high viscosity water-in-crude oil emulsions, with a separation flux of 40 L m-2 h-1 by gravity. Compared to the situation without electricity, the separation flux of water-in-crude oil emulsion has increased four-fold. The joule heating of the P-CP membrane expands its service time and application scenarios, demonstrating its great application prospects in actual viscous oil-water emulsion separation.

Does competitive action intensity influence team performance via leader bottom-line mentality? A social information processing perspective.

Leader bottom-line mentality (LBLM) exists when leaders solely focus on securing bottom-line outcomes to the exclusion of alternative considerations. Our research examines why leaders adopt LBLMs and the implications of this focused leadership strategy on team sales performance and pro-environmental behavior. Utilizing social information processing theory, we examine LBLM as a mediator and contend that competitive action intensity in the work environment provokes LBLM, which then signals to teams the importance of raising sales performance and reducing pro-environmental behavior. We also suggest that leader performance reward expectancy (i.e., perceptions that rewards are directly tied to high performance) serves as a first-stage moderator and team performance reward expectancy serves as a second-stage moderator, with higher (vs. lower) levels of each strengthening the indirect effects of competitive action intensity, through LBLM, onto team sales performance and pro-environmental behavior. Utilizing field data from a large pharmaceutical company (Study 1) as well as an experimental causal chain design (Studies 2a and 2b), we found support for our theoretical model. (PsycInfo Database Record (c) 2024 APA, all rights reserved).

Molecular Dynamics Simulations of Supramolecular Polymers within Nanoconfinements for Enhanced Oil Recovery.

Supramolecular polymers offer promising potential for enhanced oil recovery (EOR) advancing techniques. Current instrumental analyses face limitations in capturing instantaneous intracomplex motions due to temporal and spatial constraints. The molecular mechanism of supramolecular polymer transport behavior within nanoconfinement is not yet fully understood. Therefore, the self-assembly mechanism of ß-cyclodextrin (ß-CD) and adamantane (ADA)-modified supramolecular polymers (p-AA-ß-CD-ADA) was delved into in this work. Further exploration focuses on the translocation dynamics of p-AA-ß-CD-ADA within nanoconfinement under external driving forces. Results suggest that ß-CD and ADA in p-AA-ß-CD-ADA were assembled into nodes in the form of a host and a guest, combining with a "node-rebar-cement" interaction model encapsulating the formation mechanism of these supramolecular polymers. The heightened density of the hydrate layers at the nanoscale pore throats acts as a constraining factor, resulting in restricted mobility and altered dynamics of the supramolecular polymers. During passage through nanopore throats, host-guest molecules within the supramolecular polymer experience noncovalent dissociation. Notably, these supramolecular polymers exhibit remarkable self-healing capabilities, reinstating their assembly state upon traversing pore throats. This work provides a molecular-level comprehension of the potential utility of supramolecular polymers in EOR processes, offering valuable information for the molecular design of polymers employed for EOR in low-permeability reservoirs.

Impact of nanoplastics on membrane scaling and fouling in reverse osmosis desalination process.

Nanoplastics (NPs) are a prevalent type of emerging pollutant in marine environment. However, their fouling behavior and impact on reverse osmosis (RO) membrane performance remain unexplored. We investigated the relationship between polystyrene (PS), one of the most abundant NPs, with silica scaling and humic acid (HA) fouling in RO. The results demonstrated that the surface potential of NPs played an important role in the combined scaling and fouling process. Compared with the negatively charged NPs (original PS and carboxyl group modified PS, PS-COOH), the amino-functionalized PS (PS-NH2) with positive surface charge significantly accelerated membrane scaling/fouling and induced a synergistic water flux decline, due to the strong electrostatic attraction between PS-NH2, foulants, and the membrane surface. The amino groups acted as binding sites, which promoted the heterogeneous nucleation of silica and adsorption of HA, then formed stable composite pollutants. Thermodynamic analysis via isothermal titration calorimetry (ITC) further confirmed the spontaneous formation of stable complexes between PS-NH2 and silicates/HA. Our study provides new insights into the combined NPs fouling with other scalants or foulants, and offers guidance for the accurate prediction of RO performance in the presence of NPs.

A comprehensive evaluation of the temporal and spatial fouling characteristics of RO membranes in a full-scale seawater desalination plant.

The fouling of seawater reverse osmosis (SWRO) membranes remains a persistent challenge in desalination. Previous research has focused mainly on fouling separately; however, organic, inorganic, and biofouling can coexist and influence each other. Hence, in-depth study of the spatiotemporal changes in actual combined fouling in full-scale seawater desalination will provide more effective information for fouling investigation and control. In this study, we monitored (i) the operational performance of a full-scale desalination plant for 7 years and (ii) the development and characterization of membrane and spacer fouling at different locations of spiral-wound membrane modules sampled after 2.5-, 3.5-, and 7-year operation. The findings showed that (i) operational performance indicators declined with time (normalized flux 40 % reduction, salt rejection 2 % in 7 years), with a limited effect of the 20-day cleaning frequency, (ii) fouling accumulation in the membrane module mainly occurred at the feed side of the lead module and the microbial community in these area exhibited the highest diversity, (iii) the dominant microbial OTUs belonged mainly to Proteobacteria (43-70 %), followed by Bacteroidetes (10-11 %), (iv) Phylogenetic molecular ecological networks and Spearman correlation analysis revealed that Chloroflexi (Anaerolineae) and Planctomycetes were keystone species in maintaining the community structure and biofilm maturation and significantly impacted the foulant content on the SWRO membrane, even with low abundance, and that (v) fouling accumulation was composed of polysaccharides, soluble microbial products, marine humic acid-like substances, and inorganic Ca/Fe/Mg/Si dominate the fouling layer of both the membrane and spacer. Overall, variation partitioning analysis quantitatively describes the increasing contribution of biofouling over time. Ultimately, the organic‒inorganic-biofouling interaction (70 %) significantly contributed to the overall fouling of the membrane after 7 years of operation. These results can be used to develop more targeted fouling control strategies to optimize SWRO desalination plant design and operation.

Machine learning for layer-by-layer nanofiltration membrane performance prediction and polymer candidate exploration.

In this study, machine learning-based models were established for layer-by-layer (LBL) nanofiltration (NF) membrane performance prediction and polymer candidate exploration. Four different models, i.e., linear, random forest (RF), boosted tree (BT), and eXtreme Gradient Boosting (XGBoost), were formed, and membrane performance prediction was determined in terms of membrane permeability and selectivity. The XGBoost exhibited optimal prediction accuracy for membrane permeability (coefficient of determination (R2): 0.99) and membrane selectivity (R2: 0.80). The Shapley Additive exPlanation (SHAP) method was utilized to evaluate the effects of different LBL NF membrane fabrication conditions on membrane performances. The SHAP method was also used to identify the relationships between polymer structure and membrane performance. Polymers were represented by Morgan fingerprint, which is an effective description approach for developing modeling. Based on the SHAP value results, two reference Morgan fingerprints were constructed containing atomic groups with positive contributions to membrane permeability and selectivity. According to the reference Morgan fingerprint, 204 potential polymers were explored from the largest polymer database (PoLyInfo). By calculating the similarities between each potential polymer and both reference Morgan fingerprints, 23 polymer candidates were selected and could be further used for LBL NF membrane fabrication with the potential for providing good membrane performance. Overall, this work provided new ways both for LBL NF membrane performance prediction and high-performance polymer candidate exploration. The source code for the models and algorithms used in this study is publicly available to facilitate replication and further research. https://github.com/wangliwfsd/LLNMPP/.

Nanocomposite Hydrogel Engineered Janus Membrane for Membrane Distillation with Robust Fouling, Wetting, and Scaling Resistance.

Membrane distillation (MD) is considered to be rather promising for high-salinity wastewater reclamation. However, its practical viability is seriously challenged by membrane wetting, fouling, and scaling issues arising from the complex components of hypersaline wastewater. It remains extremely difficult to overcome all three challenges at the same time. Herein, a nanocomposite hydrogel engineered Janus membrane has been facilely constructed for desired wetting/fouling/scaling-free properties, where a cellulose nanocrystal (CNC) composite hydrogel layer is formed in situ atop a microporous hydrophobic polytetrafluoroethylene (PTFE) substrate intermediated by an adhesive layer. By the synergies of the elevated membrane liquid entry pressure, inhibited surfactant diffusion, and highly hydratable surface imparted by the hydrogel/CNC (HC) layer, the resultant HC-PTFE membrane exhibits robust resistance to surfactant-induced wetting and oil fouling during 120 h of MD operation. Meanwhile, owing to the dense and hydroxyl-abundant surface, it is capable of mitigating gypsum scaling and scaling-induced wetting, resulting in a high normalized flux and low distillate conductivity at a concentration factor of 5.2. Importantly, the HC-PTFE membrane enables direct desalination of real hypersaline wastewater containing broad-spectrum foulants with stable vapor flux and robust salt rejection (99.90%) during long-term operation, demonstrating its great potential for wastewater management in industrial scenarios.

Research progress on Th22 cells and related cytokines in tumors: current status and future perspectives.

Th22 cells are a newly identified subpopulation of CD4+ T lymphocytes distinct from Th1, Th2, and Th17 cells, which secretes mainly interleukin-22 (IL-22), in addition to a variety of other cytokines. The function of Th22 cells in tumors is mainly realized through IL-22, which can activate JAK/STAT and MAPK cell signaling pathways, thereby regulating the anti-tumor immune response of the body. The main function of Th22 cells is to participate in mucosal defense, tissue repair, and wound healing. However, controversial data have shown that overexpression of IL-22 can lead to pathological changes under inflammatory conditions and tumor progression. In this review, we searched the PubMed and Web of Science databases for articles and reviews published before May 6, 2022, using the keywords "Th22 cells, T helper 22 cells, cancer, tumor", and conducted a comprehensive review of the relevant literature. In addition, this article offers an overview of the relevant findings on the function of Th22 cells in tumors published in recent years, along with a more comprehensive analysis of the functions and mechanisms of Th22 cells in tumors. This article will hopefully inspire new future directions in the research on cancer therapy.

Dual-Ligand ZIF-8 Bearing the Cyano Group for Efficient and Selective Uranium Capture from Seawater.

Uranium extraction from seawater is a potential technique that will change the world. Adsorption capacity, selectivity, and antibacterial ability for high-performance uranium adsorbents remain the major challenges. In this study, a dual-ligand zeolitic imidazolate framework 8 (ZIF-8) decorated with cyano groups (ZIF-8-CN) is prepared via a facile blend strategy at room temperature. Owing to the abundant mesopores and nitrogen functional groups, ZIF-8-CN shows an extremely high uranium uptake of 1000 mg/g at pH = 6, which is 2.42 times that of pristine ZIF-8. Noteworthily, ZIF-8-CN possesses a 16.2 mg/g uranium adsorption in natural seawater within 28 days, and the distribution coefficient (Kd = 3.25 × 106 mL/g) is far greater than that for other coexisting metal ions, demonstrating a marked preference for uranyl ions. Except for the coordination between uranium and nitrogen in imidazole, the cyano groups provide additional adsorption sites and preferentially bind to uranyl, thereby strengthening the affinity for uranyl. Notably, ZIF-8-CN displays ultrastrong antimicrobial ability against both Escherichia coli and Staphylococcus aureus, which is greatly desired for the scale-up marine tests. Our study demonstrates the high potential of ZIF-8-CN in uranium capture and provides a wide scope for the application of mixed-ligand MOFs.

MXene/Graphene modified cellulose aerogel for photo-electro-assisted all-weather cleanup of high-viscous crude oil from spill.

The frequent occurrence of oil spills has led to serious environmental pollution and ecological issues. Given the high-viscosity of crude oil, it is essential to develop sorbents with efficient viscosity reduction and sorption capacity in various environmental conditions. Herein, a superhydrophobic carboxymethyl cellulose (CMC) aerogel co-modified by MXene and graphene jointly (M-Mxene/Gr CA) with aligned channels structure was prepared. The aligned channels structure can effectively improve the longitudinal thermal conductivity and reduce the sorption resistance. Through the modification of MXene and graphene, the aerogel realized efficient photo/electro-thermal conversion, thus ensuring its adaption to various working environments. The rapid heat generation can significantly reduce the viscosity of crude oil, achieving rapid recovery. Under one sun illumination (1.0 kW/m2), the surface temperature of M-Mxene/Gr CA can reach 72.6 °C and its sorption capability for high-viscous crude oil reaches 18 g/g. Combining photo-thermal and electro-thermal (0.5 kW/m2 and 23 V), the average sorption rate of crude oil can reach 1.3 × 107 g m-3 s-1. Finally, we present a continuous sorption system to recover offshore oil spills under the assistance of a pump. This work provides a new option for tackling high-viscous offshore oil spills due to its environmental friendliness and fast sorption capacity.

Intrinsic mechanism for the removal of antibiotic pollution by a dual coagulation process from the perspective of the interaction between NOM and antibiotic.

Antibiotics bring potential risks to human health and ecosystem, and their coexistence with natural organic matters (NOMs) could have harmful impacts on the environment. Herein, a polyaluminium chloride (PAC)-polydimethyl diallyl ammonium chloride (PDMDAAC) dual coagulation process was designed to remove the co-pollutants of chlortetracycline (CTC) and humic acid (HA), representing antibiotics and NOMs, respectively. The main research strength was given to understand molecular interactions and their mechanisms associated with the coagulation and flocculation. We found that the co-existing HA and CTC increased the hydrophily and stability of contaminants, and generated HA@CTC complexes with large particles size. The interaction mechanism between CTC and HA was mainly hydrogen bonding, hydrophobic association action, n-π* electron donor-acceptor interaction, and π-π* conjugation. Lewis acid-base interaction was the main force between HA and CTC. The bonding energies of OH…N, OH…O, and hydrophobic association were -12.2 kcal/mol, -13.1 kcal/mol, and -11.4 kcal/mol, respectively, indicating that hydrogen bonding was stronger than hydrophobic association. The interactions between HA and CTC could improve their removal efficiency in the coagulation process. This is due to that the functional groups (COOH and OH) in the HA@CTC could be adsorbed by Al based hydrolysates. Polar interaction dominated the CTC and HA removal, and PAC was more efficient than PDMDAAC to remove HA@CTC complexes due to its higher complexing capacity. Thanks to the low concentration of residual contaminants and the formation of large and loose flocs, the interaction of HA and CTC could alleviate membrane fouling during ultrafiltration process. This study will provide new insight into the efficient removal of combined pollution and membrane fouling control.

Coupling Carbon-Based Composite Phase Change Materials with a Polyurethane Sponge for Sustained and Efficient Solar-Driven Cleanup of Viscous Crude Oil Spill.

The efficient cleanup of crude oil spills is a worldwide problem due to their high viscosity and low fluidity. Under the assistance of solar radiation, adsorbents with in situ heating function are becoming the ideal candidates to solve this problem. In this study, a new strategy coupling a polyurethane (PU) sponge with phase change materials (PCMs) is proposed to realize the efficient utilization of solar energy and crude oil cleanup. Wormlike carbon nanotubes/mesoporous carbon (CNTs/MC) with a core-shell structure was used to encapsulate polyethylene glycol (PEG), which was then introduced into the PU sponge for photothermal conversion and thermal storage. After coating with a polydimethylsiloxane (PDMS) layer, the sponge was further endowed with hydrophobic characteristics. Additionally, PDMS can function as a binder between PEG@CNTs/MC and sponge skeleton. The resulting PEG@CNTs/MC/PU/PDMS (named as PEG@CMPP) exhibited excellent photothermal conversion and high absorption capacity for high-viscosity crude oil. Most importantly, thanks to the heat storage properties of PEG, the stored heat can be sustainably transferred to the surrounding crude oil to promote its continuous absorption even under insufficient light intensity conditions. The crude oil absorption capacity of PEG@CMPP-3 reached approximately 0.96 g/cm3 even after the light source was removed, which manifested the distinctive advantages compared to the conventional photothermal adsorbent. The proposed approach integrates the high efficiency of solar-assisted heating and energy-conserving advantage, thereby providing a feasible strategy for highly efficient remediation of viscous crude oil spills.

Janus Membrane with Hydrogel-like Coating for Robust Fouling and Wetting Resistance in Membrane Distillation.

Membrane distillation (MD) is a promising technique for water reclamation from hypersaline wastewater. However, fouling and wetting of the hydrophobic membranes are two prominent challenges for the widespread application of MD. Herein, we developed an antiwetting and antifouling Janus membrane comprising a hydrogel-like polyvinyl alcohol/tannic acid (PVA/TA) top layer and a hydrophobic polytetrafluoroethylene (PTFE) membrane substrate via a facile and benign strategy combining mussel-amine co-deposition with the shrinkage-rehydration process. Interestingly, the vapor flux of the Janus membrane was not compromised, though a microscale PVA/TA layer was introduced, possibly due to the high water uptake and reduced water evaporation enthalpy of the hydrogel-like structure. Moreover, the PVA/TA-PTFE Janus membrane sustained stable MD performance while treating a challenging saline feed containing surfactants and mineral oils. The robust wetting resistance arises from the synergistic effects of the elevated liquid entry pressure (1.01 ± 0.02 MPa) of the membrane and the retardation of surfactant transport to the substrate PTFE layer. Meanwhile, the hydrogel-like PVA/TA layer hinders oil fouling due to its strongly hydrated state. Furthermore, the PVA/TA-PTFE membrane exhibited improved performance in purifying shale gas wastewater and landfill leachate. This study provides new insights into the facile design and fabrication of promising MD membranes for hypersaline wastewater treatment.

Mesoporous carbon hollow spheres encapsulated phase change material for efficient emulsification of high-viscosity oil.

Low fluidity of high-viscosity oil usually hinders its emulsification. Facing this dilemma, we proposed a novel functional composite phase change material (PCM) with in situ heating feature coupled with emulsification capability. This composite PCM consisting of mesoporous carbon hollow spheres (MCHS) and polyethylene glycol (PEG) shows excellent photothermal conversion ability, thermal conductivity and Pickering emulsification. Compared with the currently reported composite PCMs, the unique hollow cavity structure of MCHS not only enables excellent encapsulation of PCM, but also protects the PCM from leaking and direct contact with oil phase. Importantly, the thermal conductivity of 80% PEG@MCHS-4 was determined to be 1.372 W/m·K, which was 2.887 times superior to that of pure PEG. MCHS endows the composite PCM with excellent light absorption capacity and photothermal conversion efficiency. The viscosity of high-viscosity oil can be facilely reduced in situ once it comes into contact with the heat-storing PEG@MCHS, thus the emulsification is greatly enhanced. In view of the in situ heating feature and emulsification capability of PEG@MCHS, this work puts forward a novel solution to address the problem of emulsification of high-viscosity oil through the integration of MCHS and PCM.

Multi-energies assisted and all-weather recovery of crude oil by superhydrophobic melamine sponge.

Efficient and safe recovery of high-viscosity marine crude oil spills is still a worldwide challenge. High-viscosity crude oil is difficult to be removed by traditional adsorbent materials. Although some recent developments in photothermal or electric-thermal oil-absorbing materials, the vertical heat transfer inside and the potential hazard of electrical leakage are difficult to be guaranteed. In order to overcome these problems, we polymerized dopamine (DA) in situ on the skeleton surface of the commercial melamine sponge (MS), and further coated the full-wavelength light-absorbing Fe3O4 NPs-Graphene (HF-G) on it to obtain the superhydrophobic sponge with excellent photothermal conversion effect, heat conductivity and magnetic heating capabilities (HF-G/PDA@MS). When the thickness of sponge is 5 mm, the HF-G/PDA@MS shows excellent vertical heat conductivity ability, and can absorb about 80 g/g. It also can be combined with an extra electric-heating device to achieve continuous heating to reduce the viscosity and recover crude oil at night or extreme weather. In addition, the temperature of HF-G/PDA@MS can reach about 40 °C by electromagnetic induction heater, indicating that we can use multiple energies-assisted modes to heat the HF-G/PDA@MS to. This work provides a promising solution and theoretical support for all-weather solving offshore crude oil spills pollution and recovery.